Thursday, November 13, 2014

Article Number: 9937




MSDS - CALCIUM FLUORIDE





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1 - PRODUCT IDENTIFICATION



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PRODUCT NAME: CALCIUM FLUORIDE



FORMULA: CAF2



FORMULA WT: 78.08



CAS NO.: 7789-75-5



NIOSH/RTECS NO.: EW1760000



COMMON SYNONYMS: FLUORITE; FLUORSPAR



PRODUCT CODES: 1354



EFFECTIVE: 09/02/86



REVISION #02





PRECAUTIONARY LABELLING



BAKER SAF-T-DATA(TM) SYSTEM





HEALTH - 1 SLIGHT



FLAMMABILITY - 0 NONE



REACTIVITY - 0 NONE



CONTACT - 1 SLIGHT



HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).





LABORATORY PROTECTIVE EQUIPMENT





SAFETY GLASSES; LAB COAT





PRECAUTIONARY LABEL STATEMENTS





WARNING



CAUSES IRRITATION



AVOID CONTACT WITH EYES, SKIN, CLOTHING.



KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.





SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)





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2 - HAZARDOUS COMPONENTS



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COMPONENT % CAS NO.





CALCIUM FLUORIDE 90-100 7789-75-5





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3 - PHYSICAL DATA



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BOILING POINT: 2500 C ( 4532 F) VAPOR PRESSURE(MM HG): N/A





MELTING POINT: 1403 C ( 2557 F) VAPOR DENSITY(AIR=1): N/A





SPECIFIC GRAVITY: 3.18 EVAPORATION RATE: N/A



(H2O=1) (BUTYL ACETATE=1)





SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0





APPEARANCE & ODOR: ODORLESS, WHITE POWDER OR CUBIC CRYSTALS.





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4 - FIRE AND EXPLOSION HAZARD DATA



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FLASH POINT (CLOSED CUP: N/A





FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %





FIRE EXTINGUISHING MEDIA



USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.





SPECIAL FIRE-FIGHTING PROCEDURES



FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED



BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.





TOXIC GASES PRODUCED



HYDROGEN FLUORIDE





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5 - HEALTH HAZARD DATA



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THRESHOLD LIMIT VALUE (TLV/TWA): 2.5 MG/M3 ( PPM)





PERMISSIBLE EXPOSURE LIMIT (PEL): 2.5 MG/M3 ( PPM)





TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 4250



LD50 (IPR-MOUSE)(MG/KG) - 2775





CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO





EFFECTS OF OVEREXPOSURE



DUST MAY IRRITATE SKIN OR EYES.



INGESTION MAY CAUSE GASTROINTESTINAL PAIN.



INGESTION IS HARMFUL AND MAY BE FATAL.





TARGET ORGANS



EYES, SKIN, RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, KIDNEYS





MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE



NONE IDENTIFIED





ROUTES OF ENTRY



INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT





EMERGENCY AND FIRST AID PROCEDURES



INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE



LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.



INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED



PERSON TO FRESH AIR. GET MEDICAL ATTENTION.



EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15



MINUTES. GET MEDICAL ATTENTION.



SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST



15 MINUTES.





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6 - REACTIVITY DATA



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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR





CONDITIONS TO AVOID: NONE DOCUMENTED





INCOMPATIBLES: STRONG ACIDS





DECOMPOSITION PRODUCTS: HYDROGEN FLUORIDE





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7 - SPILL AND DISPOSAL PROCEDURES



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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE



WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.



WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND



COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.





DISPOSAL PROCEDURE



DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL



ENVIRONMENTAL REGULATIONS.





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8 - PROTECTIVE EQUIPMENT



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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET



TLV REQUIREMENTS.





RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION



CONDITIONS EXIST. IF AIRBORNE CONCENTRATION



EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS



IS ADVISED.





EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE



RECOMMENDED.





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9 - STORAGE AND HANDLING PRECAUTIONS



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SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)





SPECIAL PRECAUTIONS



KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE



AREA.





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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION



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DOMESTIC (D.O.T.)





PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)





INTERNATIONAL (I.M.O.)





PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)


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